The California Highway Patrol says a semi-truck was heading west on Annadale when it began to turn south onto Chestnut.
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That's when a pickup heading north ran into the big rig, getting pinned underneath.
Both a man and woman in the pickup died at the scene.
The driver of the semi was not hurt.
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Officers are still investigating what led up to the crash.
The victims have not yet been identified.
Officers say foggy conditions may have been a factor in the crash.