It happened just before 3 am Monday on Highway 33 at Bass Avenue.
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Officers say a 27-year-old man from Mendota was driving a Chevy Equinox south, just north of Bass Avenue.
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They say he ended up crossing over into the northbound lanes of Highway 33 and hit a Toyota Corolla driven by another man from Mendota.
The driver of the Toyota died at the scene.
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The driver of the Chevy suffered moderate injuries and was arrested for DUI.
Stay with ABC30 for the latest details on this developing story.