It caught fire about 1 am Tuesday on northbound Betty Drive in Goshen.
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Tulare County Fire officials say the truck blew a tire, which sparked the fire.
The truck was carrying an assortment of chemicals.
The driver pulled over to a safe spot, disconnected the trailer and pulled away.
Officials said the fire spread to some nearby pallets, but they were quickly put out.
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They are currently letting the trailer fire burn itself out.
There is a Hazmat unit at the scene, but they are not actively fighting the fire.
One lane is closed and traffic is able to pass in the remaining two northbound lanes.